Controlled aqueous polymerization of acrylamides and acrylates and “in situ” depolymerization in the presence of dissolved CO2
- Lloyd, Danielle J.
- Nikolaou, Vasiliki
- Collins, Jennifer
- Waldron, Christopher
- Anastasaki, Athina
- Bassett, Simon
- Howdle, Steven M.
- Blanazs, Adam
- Wilson, Paul
- Kempe, Kristian
- Haddleton, David M.
Publication date
April 2016
DOI Publisher
Royal Society of Chemistry (RSC) ISSN
1359-7345 Citation count (estimate)
2Abstract
Aqueous copper-mediated radical polymerization of acrylamides and acrylates in carbonated water resulted in high monomer conversions (t t > 10 min). The regenerated monomer was characterized and repolymerized following deoxygenation of the resulting solutions to reyield polymers in high conversions that exhibit low dispersities
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